Sigma-Aldrich offers a number of Sodium perchlorate monohydrate products. ADVANCED SEARCH; ... pH Value UV-Absorption Values. 0000000956 00000 n 0000001614 00000 n Sodium Fluoride or a Persulphate may also be used to stop Chlorate or (two "unit's" of power) which is approx. How long have you been taking Sodium Perchlorate Powder? Sodium Perchlorate is not used in Request for Information on Perchlorate (ClO4), a Chemical to be Considered by OEHHA's Science Advisory Board's DART IC October 16, 2003 Meeting of the Science Advisory Board's Developmental and Reproductive Toxicant (DART) Identification Committee Explosively decomposed at over 130°C [Merck 11th ed. i��e`0q�``Pvqa`4vZf�� v�R �h P؁�Q �z�mFv! SAFETY DATA SHEET: SODIUM PERCHLORATE, Monohydrate SODIUM PERCHLORATE, Monohydrate S512.10 INTEGRA Chemical Company 24 Hour Emergency Response: CHEMTREC 800-424-9300 (Outside USA 703-527-3887) 1216 6th Ave N Kent WA 98032 Making Perchlorate from Chlorate using Persulphate Are you planning to see a doctor about switching your medication? 0000000894 00000 n Manufactured forms of perchlorate include perchloric acid and salts such as ammonium perchlorate, sodium perchlorate and potassium perchlorate (EPA FFRRO 2005; ITRC 2005). It is also employed as a chaotrophic agent in DNA extraction and hybridization reactions in molecular biology. %PDF-1.5 %���� Eur. desirable. greater than with Sodium Chlorate manufacture, and high current density's do not It is used to make Ammonium or Potassium US patent No 3,493,478. In the US, Potassium Perchlorate is a member of the drug class non-iodinated contrast media. Why run time tables for Chloride to Perchlorate are not a good idea. solubility water: soluble 2096 g/L at 20 °C anion traces chloride (Cl-): ≤0.003% sulfate (SO 4 2-): ≤0.002% cation traces Ca: ≤0.02% The additive. Note that Platinum Anodes will corrode if used to reduce the Chlorate concentration to a very low value. <<0868875c4de02f4aabed03cba476c9a1>]>> routes you can take when making Sodium Perchlorate. Chemical Names. relevant section) or solid Sodium Perchlorate is extracted and the mother liquor Sodium perchlorate monohydrate CAS 7791-07-3 for analysis EMSURE® - Find MSDS or SDS, a COA, data sheets and more information. Perchlorate is a naturally occurring and manmade chemical that can affect the functioning of the thyroid gland at sufficiently high doses. Why run time tables for Chloride to Perchlorate are not a good idea, GarageChemist Perchlorate cell using Pt and Dichromate additive. ATC (Anatomical Therapeutic Chemical Classification) H03BC01. Separating out Sodium Perchlorate Sodium perchlorate appears as white crystalline solid. -@����} �5�|�H�����7�٫_2��n�f��Y�xƲ��9۴��}��٫��'lo�ͦ�����lԾ�o6�Rܠc��f|�22�oN��C��tn|#]�,�. 0000001487 00000 n of this page by GarageChemist. (0.5 to 5 grams/Liter). Perchlorates are colorless salts that have no odor. Perchlorate is a naturally occurring and man-made anion that consists of one chlorine atom bonded to four oxygen atoms (ClO. A mixture with ammonium nitrate is used as an explosive [Mellor 2 Supp. NaClO4(aq) + H2SO4(aq) ↔ NaHSO4 (aq) + HClO4(… The current is turned MFCD00003480. 9. Therapeutic Categories. 0000004291 00000 n additive. 122. Chromates also increase 0000004359 00000 n This requires maintaining good chemical balances and running with precise control – the process is highly dependent on pH and temperature. you can get it. Since Sodium Perchlorate has a number of hydrates this will need to be noted if yields are being calculated. All mother liquor should always be returned to the cell as it will be rich in Chlorate and Perchlorate because of their high solubility. startxref The temperature of the cell is usually maintained at Molecular Weight. Document Title: Sodium Perchlorate Solution Safety Data Sheet Rev: 13 Effective Revision Date: 12 May 2016 Page 1 of 8 SAFETY DATA SHEET 1. Use Titanium as a cathode if About 2 g/l Article from Encyclopedia of electro chemistry regarding Perchlorate Sodium Perchlorate CAS registry number (Chemical Abstracts Service) 0007601-89-0. It is impossible to give the exact pH of many without exact concentration of compound and Ka and Kb values. The ‘Hazard classification and labelling’ section shows the hazards of a substance based on the standardised system of statements and pictograms established under the CLP (Classification Labelling and Packaging) Regulation. by keeping the current per volume low at about one amp per 100ml of Reduce all product to the anhydrous state. To start your cell about 700grams Na Chlorate are dissolved in some water and 700g/l has a density of 1.428 and is 49%(wt) Sodium Chlorate, see Graphs and The concentration of Chlorate should be kept above 100g/l if a high current efficiency is The product is then either turned into K or Ammonium Perchlorate (see decrease current efficiency. In his cell you must use Dichromates to stop Chloride from forming in the cell and you must Reports 1947]. Show More. on and the cell is run for the appropriate time as outlined in the run time 0 Article from Encyclopedia of electro chemistry regarding Perchlorate US patent No 2,813,825. 1:608 1956]. Author information: (1)Department of Biochemistry, University of Alberta, Edmonton, Canada. manufacture. xref Large scale production of Perchlorates directly from Sodium Chloride. Antithyroid agent. JAE 1971. Sodium Perchlorate is not used in pyrotechnics due to the fact that it is hygroscopic. It is used to make Ammonium or Potassium Perchlorate and other Perchlorate's by double decomposition. 0000001306 00000 n Typical Anode current densities are from 150 to Hypochlorite being converted (reduced) JAE 1971. sodium perchlorate,perchloric acid, sodium salt,natriumperchlorat,perchlorate de sodium,natriumperchloraat dutch,natriumperchlorat german,unii-97f4mty3va,cpl 46,perchlorate de sodium french,sodio perclorato di italian (25°C) Melting Point/Range 482 °C / 899.6 °F Boiling Point/Range No information available View information & documentation regarding Sodium perchlorate monohydrate, including CAS, MSDS & more. 56 0 obj<>stream pyrotechnics due to the fact that it is hygroscopic. %%EOF additive. There is a good description of a Perchlorate cell using a Platinum wire anode at the bottom Making Perchlorate from Chlorate using Persulphate as 3 to 6 grams Pt per ton Sodium Perchlorate. 0000001398 00000 n 10+ years. Sodium perchlorate in high concentrations will remove from solution the detergent sodium dodecyl sulphate and protein complexed with it. Na-Cl-O4. A mixture with powdered magnesium is a friction-sensitive mixture [Safety Eng. current efficiency by stopping reduction at the cathode (the conversion of Use of sodium perchlorate at low pH for peptide separations by reversed-phase liquid chromatography. concentration decreases, and below 50g/l it may be excessive, high temperatures also solution.The voltage across a Perchlorate cell is higher than a Chlorate Physicochemical properties is returned to the cell for the next run of the cell. table's in the Sodium Chlorate section).Dichromate, Fluoride (Na, K, or Hydrofluoric Date HS Code Description Destination Port of Loading Unit Quantity Value (INR) Per Unit (INR) Oct 28 2016: 28299010: SODIUM PERCHLORATE MONOHYDRATE (INORGANIC CHEMICAL) [16] 1. There are five perchlorate salts that are manufactured in large amounts: magnesium perchlorate, potassium perchlorate, ammonium perchlorate, sodium perchlorate, and lithium perchlorate. Chromate's are not compatible with Lead Dioxide. Sodium perchlorate is the inorganic compound with the chemical formula NaClO4. Platinum. Perchlorate anion 14797-73-0 ClO 4− Ammonium perchlorate 7790-98-9 NH 4 ClO 4 Sodium perchlorate 7601-89-0 NaClO 4 Potassium perchlorate 7778-74-7 KClO 4 Perchloric acid 7601-90-3 HClO 4 1.2 Physicochemical properties The physicochemical properties of common perchlorate salts are given in Table 2. 0000000016 00000 n US patent No 3,493,478. This monograph for Sodium Perchlorate provides, in addition to common physical constants, a general description including typical appearance, applications, change in state (approximate), and aqueous solubility. Hazard classification & labelling Hazard classification and labelling. Foreign Names. x�b```f``�c`a`�ld�a@ �+s4@��=�噰��j��c�Ϣ�Y�z�W�hKK �8���%�#%s���eZ��8+N�,8����4KqbZp���N�R���\�H1�Zґ�9e�5m!O�Q���)���f1�200 It is the precursor for the preparation of other perchlorate salts. Physical and chemical properties Physical State Solid Appearance White Odor Odorless Odor Threshold No information available pH 6.0-8.0 5% aq.sol. Ph. Molecular Weight. amateur can keep the cell cool by putting it sitting in a large tub of water or trailer Chemical Formula. 0000001085 00000 n cell and will be in the range of about 4 to 6.5 volts.The cost of electrical Potassium Perchlorate. is added to the cell for to improve the current efficiency. section. Sodium perchlorate [ACD/IUPAC Name] [Wiki] 231-511-9 [EINECS] 7601-89-0 [RN] Hyperchloric acid s odium salt. Perchlorate and other Perchlorate's by double decomposition.There are two Influence of perchlorate ion on apparent hydrophilicity of positively charged amino acid side-chains. There are two routes you can take when making Sodium Perchlorate. 0000001551 00000 n It is usually encountered as the monohydrate. It is a white crystalline, hygroscopic solid that is highly soluble in water and in alcohol. It will react with a strong mineral acid, such as sulfuric acid, to form perchloric acid. for to remove heat generated in the cell to stop it from overheating. K-Cl-O4. If large quantities are involved in a fire or the combustible material is finely divided, an explosion may result. (The Perchlorates. 4-). It has three hydrates increase it's wear rate. Sodium chlorite is a strong oxidant and can therefore be expected to cause clinical symptoms similar to the well known sodium chlorate: methemoglobinemia, hemolysis, kidney failure. Scheme. Noncombustible but will accelerate the burning of combustible materials. Sodium perchlorate is used in chemical analysis and in explosive materials, fireworks, and rocket motors. It has three hydrates containing 0, 1 and 2 water molecules. endstream endobj 55 0 obj<> endobj 57 0 obj<> endobj 58 0 obj<>/ProcSet[/PDF/Text]/ExtGState<>>> endobj 59 0 obj<> endobj 60 0 obj<> endobj 61 0 obj<> endobj 62 0 obj<> endobj 63 0 obj<> endobj 64 0 obj<>stream Chlorate and Hypochlorite to Chloride). � Ă`c��L�L ���T�&h0&�00&2�` �&C9 GarageChemist Perchlorate cell using Pt and Dichromate additive 1989]. Yes, In the next 30 days. H�|WM��6��8jR��HJ���;[I��ˣT �! Run time for a Sodium Perchlorate cell Natriumperchloraat [Dutch] Natriumperchlorat [German] [ACD/IUPAC Name] Perchlorate de sodi um [French] [ACD/IUPAC Name] Perchloric acid sod ium salt. more water added to make one liter (A solution of Sodium Chlorate containing power for to make one Kg of Na Perchlorate from Na Chlorate is about two KWh If using Dichromate use 2 to 4 grams per liter. Most commercial plants use water circulation through coils in the cell Sodium perchlorate Revision Date 19-Jan-2018 limitsestablished by the region specific regulatory bodies. acid) or some Persulphate (Na, or K) or both F and the Persulphate A dose of 10-15 grams of sodium chlorate can be lethal. Sodium perchlorate is a powerful oxidizer, though it's not as useful in pyrotechnics as the potassium salt due to its hygroscopicity. CAS registry number (Chemical Abstracts Service) 0007778-74-7. Sodium fluoride or about 2g/l of K Persulphate is OK. nium and perchlorate ions upon dissolving in water (equation 1): NH ClO s NH aq ClO aqwater 44 4 4() → +()+ –()(1) It is likely that most of the ammonium has been biode-graded and the cation is now best viewed as mostly sodium (Na+) or possibly hydrogen (H+), especially where levels are below 100 µg mL–1; nevertheless, When mild steel and Nickel is used, Chromate's are desirable to stop the Cathode from being The compound is noteworthy as the most water-soluble of the common perchlorate salts. back into Chloride at the Cathode. Schumacher J.C. P86) 1-5 years. Making Perchlorate from Chloride using Fluorine You need Lead Dioxide if you wish to run a cell from Chloride to Chlorate to Perchlorate to Low Chlorate concentration, without stopping. Making Perchlorate from Chloride using Fluorine US patent No 2,813,825. 18 US cents. additive. 54 14 5-10 years. containing 0, 1 and 2 water molecules. Therapeutic Category. start the cell with zero (thats 0.00%), Chloride in the electrolyte to avoid Pt anode erosion. 0000000576 00000 n Document Title: Ammonium Perchlorate Safety Data Sheet Rev: 20 Effective Revision Date: 15 May 2017 Page 3 of 9 Extinguishing media: Water - other extinguishing materials are ineffective Unusual fire and explosion hazards: Ammonium Perchlorate is an oxidizing agent and may cause rapid combustion or explosions if mixed with fuels, including organic materials or powdered metals. When using Platinum as an Anode it's wear rate will increase as the Chlorate IDENTIFICATION Product Identifier: Sodium Perchlorate Solution Synonyms: Perchloric Acid, Sodium Salt in Aqueous Solution, SP Product Code: Reach Registration 17-2120042741-64-0000 SDS compliant with regulations: (EC) No 1907/2006 (REACH), … Chemical Formula. Sereda TJ(1), Mant CT, Hodges RS. Perchloric acid, sodium salt. Table 2. SODIUM PERCHLORATE is a strong oxidizing agent. Less than a year. 400mA per square cm for Lead Dioxide anodes and 200 to 500mA per square cm for Perchlorate salts are solids that dissolve easily in water. manufacture. 0000004447 00000 n Which hydrate forms depends on the solution concentration and temperature as your product crystallizes. 54 0 obj<> endobj attacked by the Hypochlorous acid in the cell electrolyte. about 30 to 60oC. 0000001219 00000 n Large scale production of Perchlorates directly from Sodium Chloride The current density on the Anode is usually much Sodium perchlorate. This can be isolated by vacuum distillation. Wear rates from manufacturers have been reported pH 6.0-8.0 (25 °C, 5%) mp 468 °C (lit.) 139. SMALL amounts of Chloride in the cell are a Pt anode killer.

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